![]() Stable herbiciding emulsifiable concentrate
专利摘要:
1473105 Ketone solutions of mixed herbicides LILLY INDUSTRIES Ltd 8 Aug 1974 [10 Aug 1973] 37945/73 Heading A5E A stable liquid herbicidal composition comprises a dinitroaniline herbicide and a N-aryl- N'-alkoxy urea herbicide dissolved in a non- phytotoxic alicyclic ketone, the ratio of dinitroaniline to urea being from 4:1 to 1:4. Optional ingredients are other solvents and non-ionic or anionic emulsifiers containing no free alcohol or polyalcohol. Typical composition ingredients are N, N-dipropyl-4-trifluoromethyl-2, 6-dinitroaniline, N-ethyl-N-2-methylallyl-4-trifluoromethyl-2, 6-dinitroaniline, N. N- dipropyl-4-sulphamoyl-2, 6-dinitroaniline: N-(3, 4-dichlorophenyl)-N'-methyl-N'-methoxy urea; and cyclohexanone or 3, 5, 5-trimethylcyclohex-2-en-1-one. The compositions may be diluted with water and used for combating weeds in crops. 公开号:SU1243606A3 申请号:SU742054979 申请日:1974-08-09 公开日:1986-07-07 发明作者:Лидл Рой 申请人:Лилли Индастриз Лимитед (Фирма); IPC主号:
专利说明:
This invention relates to a plant protection agent, thermoglobin {, namely, a stable herbicidal emulsifiable concentrate based on a mixture. two active herbicides. The aim of the invention is to increase stability. The concentrate is obtained by dissolving the required amounts of N, N-dipropyl-4-trifluoromethyl-2,6-dinitroaniline (trifthuralin) and N- (3, i dichlorophenyl) -N-methyl-N-methoxy-chevine (3,5,5,5 linuron) trimethylcyclohex 2-en-1-one and with a large amount of aromatic solvent ao-chlorotoluene. The solution is filtered and emulsified, having previously checked that the emulsifier does not contain free alcohol, with stirring. Then the rest of the aromatic is poured Trifluralin, .100% Linuron, 100% Agent stefan 603-1 Agent stefan 603-2 Acetone Dimethylformamide dimethyl sulfoxide To simulate industrial use, small amounts of each emulsifiable concentrate are added to a large volume of water (1 g to 100 ml) and the diluted emulsions are mixed in an apparatus designed to mix the solutions in bottles by rotating in any solvent, the solution is filtered, it is packaged. Example 1. The study of the stability of the concentrate. The composition of the emulsifiable concentrate (EAF-190), g / l: Trifluralin, 100% 240 Linuron, 100% 120 Calcium dodecylbenzene-sulfonate50 Nonylphenylethoxylate 50 (agent stefan 603-1) 3 "5.5-Trimethyl-cyclohex-2-ene-he (isophorone) 150 o-chlorotoludo 1 l For comparison, the following emulsifiable concentrates are used. one. Table 1 240 120 50 50 up to 1 l up to 1 l for several hours. Next, the resulting emulsions are examined, photographed, and filtered through a Büchner funnel using a Whatman No. 1 paper filter. The paper filters are dried, re-photographed, and weighed. The data obtained are presented in Table. 2 The composition Acetone Based Based on dimethylformamide Based on dimethyl sulfoxide EAF Example 2. Conducted a test - two months after treatment The randomly selected percentage counts of four repetitions and 25 weeds were compared to untreated winter crops in neither of the randomly selected sites. EAF-190 herbicide to Prevention Occurrence Percentage of debris treated Dov. The consumption of the composition was ekkultur compared with untreated 4 l / ha, these are shown in Table. 3 Table 3 Experiment Percentage of debris compared to untreated culture 10.9 22,8 32.6 G5 Before use concentrate solids and not observed kept for a long time with the purpose of pro-bleaching, checking its stability. For example, 45 after 6 months storage at temperature. Thus, the proposed Herr 4, 25, and 37 C do not observe any biobicidal emulsifiable concentrate. decrease in stability, do not form; possesses high stability. Compiled by N. Kibalova Editor L. Gratilo Tehred L. Oleinik. Proofreader And, Muska Order 3720/59 - Circulation 679 Subscription VNIIPI USSR State Committee for inventions and discoveries 113035, Moscow, Zh-35, Raushsk nab., d, 4/5 Production and printing company, Uzhgorod, st. Project, 4 table 2 Weight of crystals B, g Dol B from A,% . 37.5 25.6 27.3 0.7
权利要求:
Claims (1) [1] . STABLE HERBICIDE EMULTIABLE CONCENTRATE, including N, C-dipropyl-4-trifluoromethyl ~ 2,6-dinitroaniline and I- (3,4-dichlorophenyl ~ -H-methyl-I-methoxyurea in a ratio of 2: 1, emulsifier and solvent, o The result is that, in order to increase stability, it contains 3,5,5-trimethylcyclohex-2 ~ en ~ 1-one, as an emulsifier - a mixture of calcium dodecylbenzenesulfonate and nonylphenylethoxylate in the ratio 1: 1, and as a solvent'-o-chlorotoluene in the following ratio of components, g / l: Mixture * · 360 Specified Emulsifier 100. 3,5,5-trimethylcyclohex-2-en-1-one 150 o-chlorotoluene The rest is up to 1 l £ N, Ν-dipropyl-4-trifluoromethyl-2,6-dinitroaniline and N- (3,4-dichloro phenyl) -I ^ methyl-I-methoxyurea in a 2: 1 ratio. and . SU ... 1243606 AZ
类似技术:
公开号 | 公开日 | 专利标题 US2863752A|1958-12-09|Herbicides DE69820677T2|2004-09-30|MICROCAPSULES WITH EASILY ADJUSTABLE DELIVERY RATE DE19961621C2|2002-11-14|Bactericidal and fungicidal liquid preparations for technical products US2709648A|1955-05-31|Herbicidal composition and method employing mixtures of a polychlorophenoxy compound with a phenyl dimethyl urea DE69635484T2|2006-08-10|HERBICIDES COMPOSITIONS CN101069501A|2007-11-14|Use of double substituted long-chain alkylamido sulfonates as crystallization inhibitor in azoles farm chemicals SU1243606A3|1986-07-07|Stable herbiciding emulsifiable concentrate GB2077104A|1981-12-16|Compositions of n-|-n'-methoxy-n'-methylurea|and 2,6-dinitro-n,n-dipropyl-4-trifluoromethylaniline | SU593641A3|1978-02-15|Method of fighting unwanted plant growth BR9610572B1|2012-02-22|herbicidal composition, process for preparing synergistically active herbicidal compositions, and processes for controlling undesirable vegetation, and for selectively controlling undesirable vegetation. AU2005211179B2|2008-07-24|Emulsifiable concentrate comprising a dinitroaniline compound EP0044955B1|1983-04-13|Liquid herbicide mixtures IE49543B1|1985-10-30|Herbicides based on pyridazones EP0592880A1|1994-04-20|Aqueous dispersion concentrate, containing linuron as active ingredient EP0017879B1|1982-06-02|Fluid formulations containing 3-|-1-methyl-1-methoxy urea and their use in combating weeds DE2042300A1|1972-03-23|Halocarboxylic acid anilides, their production and use as herbicides CH647929A5|1985-02-28|Pesticidal preparations USRE26961E|1970-10-06|Ci. aoln JPH0733605A|1995-02-03|Improved agrochemical emulsion composition JPH0585908A|1993-04-06|Stable solution type composition and emulsion type composition of herbicide propanil FI65889C|1984-08-10|N- | -N'-METHOXY-N'-METHYLUREA | OCH 2,6-DINITRO-N N-DIPROPYL-4-TRIFLUOR-METHYLANIL | INNEHAOLLANDE BESTAENDIGA EMULSION KOSPOSPOSITIONER WO2017156751A1|2017-09-21|Emulsifiable concentrates DE2310649C3|1982-05-06|Diurethanes and selective herbicidal agents containing them DE1567165C3|1978-08-17|Carbamate-based algicidal agents DE2260763C3|1979-11-29|Combating harmful organisms with dihalopropanesulfonic acid ester derivatives
同族专利:
公开号 | 公开日 JPS5944285B2|1984-10-29| IL45404D0|1974-11-29| DK140741C|1980-05-05| DE2435747C2|1987-02-26| GB1473105A|1977-05-11| CA1032362A|1978-06-06| BE818479A|1975-02-03| DD112336A5|1975-04-12| DE2435747A1|1975-02-13| NL184935B|1989-07-17| ATA654874A|1977-11-15| NL184935C|1989-12-18| RO70571A|1981-09-24| DK425074A|1975-04-21| CH596755A5|1978-03-15| PL94443B1|1977-08-31| FR2239941B1|1976-10-22| JPS5069230A|1975-06-10| SE430014B|1983-10-17| DK140741B|1979-11-12| IT1021599B|1978-02-20| AT344439B|1978-07-25| HU170845B|1977-09-28| CS185659B2|1978-10-31| NL7410591A|1975-02-12| IL45404A|1977-10-31| FR2239941A1|1975-03-07| SE7410118L|1975-02-11|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US3373010A|1964-10-08|1968-03-12|Du Pont|Herbicidal composition and method| DE1242936B|1965-03-12|1967-06-22|Schering Ag|Selective herbicides| US3322527A|1965-04-30|1967-05-30|Du Pont|Herbicidal compositions and methods employing 3--1-methyl-1-methoxyurea with 3-amino-1, 2, 4-triazole| BE705182A|1967-10-16|1968-04-16| DE1923545A1|1968-05-27|1969-12-04|Du Pont|Liquid concentrate for herbicides| BE754383A|1969-08-05|1971-02-04|Ciba Geigy|4- -3-chlorophenyl-ureas, their preparation process and their use for the destruction of parasites| CH533421A|1970-02-02|1973-02-15|Ciba Geigy Ag|Biocidal agent| DE2106884A1|1970-02-23|1971-09-16|CIBA Geigy AG, Basel |Use of phenylureas to selectively control weeds in cereals, maize, rice, cotton and soy| IL36220D0|1970-02-27|1971-04-28|Ciba Geigy Ag|Use of a phenylurea for combating weeds in wheat,oats,rye,barley,rice and cotton| IL36448A|1970-03-26|1974-07-31|Ciba Geigy Ag|N--ureas,their preparation and use as selective herbicides| IL36718D0|1970-04-30|1971-06-23|Ciba Geigy Ag|Herbicidal compositions containing phenylureas,certain new phenylureas and their preparation| DE2037265A1|1970-07-28|1972-02-03|Badische Anilin & Soda Fabrik AG, 6700 Ludwigshafen|herbicide| DE2039042A1|1970-08-06|1972-02-17|Hoechst Ag|Herbicides| DE2123185A1|1971-05-11|1972-11-30|Farbwerke Hoechst AG, vormals Meister Lucius & Brüning, 6000 Frankfurt|N-aryl ureas| CA985523A|1971-06-30|1976-03-16|American Cyanamid Company|Inhibiting plant bud growth|DE2534042A1|1975-07-30|1977-02-17|Shell Int Research|HERBICIDE MEDIUM| IT1131750B|1980-06-06|1986-06-25|Montedison Spa|STABLE FORMULATIONS OF N--N'METOXY-N'-METHYLENEAND 2,6-DINITOR-N, N-DIPROPYL-4-TRIFLUOR METHYLANILINEIN EMULSION| CH652888A5|1982-08-25|1985-12-13|Sintagro Sa|STABLE, LIQUID PREPARATION WITH HERBICIDAL EFFECT AND METHOD FOR THE PRODUCTION THEREOF.| IL116147A|1994-11-30|2002-05-23|Aventis Cropscience Sa|Emulsifiable composition for the control of insects| IL116148A|1994-11-30|2001-03-19|Rhone Poulenc Agrochimie|Emulsifiable composition for the control of insects| MA40840A|2014-10-22|2017-08-29|Ishihara Sangyo Kaisha|HERBICIDE COMPOSITION|
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申请号 | 申请日 | 专利标题 GB3794573A|GB1473105A|1973-08-10|1973-08-10| 相关专利
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